The first night will see the Scottish duo, Peter Wright and Gary Anderson face off against the American duo of Larry Butler, the former World Matchplay champion and Darin Young joining him once again.
Italy vs Canada will face off in the opening clash of the World Cup with Dawson Murschell replacing John Norman Jr in partnering John Part, the multiple time world champion.
Like alluded to Netherlands will also be involved and will face Gibraltar with Michael van Gerwen and Dyson Parody locking horns again after their classic battle at Dyson's home tournament a few years back.
Dave Chisnall will partner debutant Rob Cross and they will face the Czech Republic hoping to add to the four titles they have previously claimed. Host nation Germany with new
PDC ranking winner, Max Hopp and the brilliant prospect Martin Schindler will face Sweden in one of the ties of the round.
Other brilliant ties coming up include Republic of Ireland vs Belgium with Dimitri van den Bergh partnering Kim Huybrechts for the first time in what could be a dangerous duo. But the same can be said for Steve Lennon and William O'Connor.
Also Daryl Gurney and Brendan Dolan facing Krzysztof Ratajski and Tytus Kanik as well as Cody Harris & Warren Parry vs Paul and Harith Lim will be some of the potential ties of the round.
2018 Betway
World Cup of Darts Schedule of Play
Thursday May 31 (8pm local time)
First Round
Italy v Canada
Russia v Spain
Switzerland v China
Denmark v Brazil
Wales v Thailand
Australia v Hong Kong
Scotland v United States of America
Austria v Japan
Friday June 1 (8pm local time)
First Round
New Zealand v Singapore
Greece v Finland
Northern Ireland v Poland
Hungary v South Africa
Belgium v Republic of Ireland
England v Czech Republic
Sweden v Germany
Netherlands v Gibraltar
Saturday June 2
Afternoon Session (2pm local time)
Second Round
Wales/Thailand v Switzerland/China
Australia/Hong Kong v Russia/Spain
Austria/Japan v Italy/Canada
Scotland/USA v Denmark/Brazil
Evening Session (8pm local time)
Second Round
Belgium/Republic of Ireland v Greece/Finland
England/Czech Republic v New Zealand/Singapore
Northern Ireland/Poland v Sweden/Germany
Netherlands/Gibraltar v Hungary/South Africa
Sunday June 3
Afternoon Session (2pm local time)
Quarter-Finals
Evening Session (8pm local time)
Semi-Finals
Final