Bunting averaged 89 and took advantage of a poor performance from Scotty Dog which means he has an unbeaten record going into the next round.
Mitchell wasted darts at double and paid for it finishing 3rd in the group in the end.
Jim Williams may not be able to progress to the next round but made sure he left his mark at the Grand Slam.
He edged out Max Hopp with a 101 average in a sublime performance from the Welshman.
Also ‘The Quiff’ hit 5/6 on the doubles on his way to the win, Hopp has to now wait on the Payne result to resolve whether he progresses through.
The prize fund breakdown for this tournament can be found here. Click here for more information about the Grand Slam of Darts.
Rob Cross (98.7) 5-2 (88.66) Ryan Searle (H)
Andrew Gilding (101.52) 5-4 (104.98) Glen Durrant (F)
Simon Whitlock (108.86) 5-4 (104.58) Gerwyn Price (F)
Mensur Suljovic (90.41) 4-5 (87.06) Martin Schindler (G)
Stephen Bunting (89.97) 5-1 (91.35) Scott Mitchell (G)
Max Hopp (97.18) 4-5 (101.6) Jim Williams (E)
22:15 Peter Wright v Josh Payne (E)
22:45 Dimitri Van den Bergh v Mark McGeeney (H)